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Electrochemistry is the branch of physical chemistry that studies the relationship between electricity, as a measurable and quantitative phenomenon, and identifiable chemical change, with either electricity considered an outcome of a particular chemical change or vice-versa. These reactions involve electric charges moving between electrodes and an electrolyte (or ionic species in a solution). Thus electrochemistry deals with the interaction between electrical energy and chemical change.
When a chemical reaction is caused by an externally supplied current, as in electrolysis, or if an electric current is produced by a spontaneous chemical reaction as in a battery, it is called an electrochemical reaction. Chemical reactions where electrons are transferred directly between molecules and/or atoms are called oxidation-reduction or (redox) reactions. In general, electrochemistry describes the overall reactions when individual redox reactions are separate but connected by an external electric circuit and an intervening electrolyte.
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